Chemical industry

Filling of hazardous substances

The purpose of this safety instruction is to address essential aspects for safe filling of with hazardous substances. learning. The set of slides is intended to assist managers for the personal instruction of employees and to start an open discussion on the topic of occupational safety.

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Management of Hazardous Substances

This brochure presents the consequences of legislation on the handling of hazardous substances with the focus on health protection in the workplace.

Starting from the European legal framework for the handling of hazardous substances at the workplace, the respective national legal implementations in Austria, France, Germany, Italy, and Spain will be shown. The most important laws, regulations, and rules will be briefly outlined.

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Ready to use hazardous substances?

This brochure explains the most relevant aspects when handling hazardous substances. Using hazardous chemical agents can lead to risks to the safety and health of workers, such as irritation, poisoning, and burns. Long-term effects, emanating, for example, by carcinogenic agents, can cause occupational diseases. Furthermore, chemical agents with physical hazards have the potential to cause accidents like fire and explosion. Chemical agents with hazards for the environment can constitute risks for aquatic life and the ozone layer.

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ISSA-Instruction “Reactive chemicals and chemical reactions”

This safety instruction points out some aspects of plant and process safety. Chemical reactions often release energy – they are exothermic and produce heat. If this heat is dissipated in a controlled manner, the process is safe. Deviations in the course of the reaction or insufficient cooling may lead to a dangerous runaway reaction. The prerequisites for a safe implementation and management of chemical processes therefore include knowledge and control of the process parameters.

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ISSA-Instruction “Handling hazardous substances: occupational hygiene measures”

This safety instruction points out some important aspects for the safe handling of hazardous substances which may endanger health. In particular, the lessons describe basic occupational hygiene measures and complement the safety instructions on the topic of “Handling hazardous substances". The training tool is intended to assist managers for the personal instruction of employees and to start an open discussion on the topic of occupational safety. The safety briefing set enables superiors to share their knowledge about safe working to their subordinates and colleagues, especially with vulnerable groups.

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ISSA-Instruction "Handling Chlorine Gas Cylinders"

Chlorine is a toxic gas. Nevertheless, it is used for many tasks, e.g. for disinfection in swimming baths. Changing the gas cylinders has to be done very carefully, but without fear. This short safety instruction can be used to highlight specific aspects of handling gas cylinders especially in public swimming bath. The safety briefing set enables superiors to share their knowledge about safe working to their subordinates and colleagues, especially with vulnerable groups.

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ISSA-Instruction "Hazardous Substances"

Working with hazardous substances may be dangerous for safety and health. Therefore, at least some basic information is required. This short safety instruction can be used to highlight specific aspects of handling hazardous substances at the workplace, in particular for small and mediumsized enterprises. The safety briefing set enables superiors to share their knowledge about safe working to their subordinates and colleagues, especially with vulnerable groups.

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Carcinogenic and mutagenic chemicals. Working safely

This booklet provides useful information about: 

  • use of carcinogenic and/or mutagenic chemicals at workplaces
  • management of the risks related to exposure to such chemicals.
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ISSA-Instruction Maintenance in Plants with High Safety Requirements

Maintenance is part of the usual business in process plants. As indicated in various legal and technical standards, the instruction of workers for safety topics is crucial. In practice, it is very difficult to ensure safety. The accident rate of maintenance work is still a major focus point. 

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An information system for the implementation of the new legislation on chemical risk, particularly addressed to SMEs

Several national institutions have developed specific operational tools to support – especially SMEs – in carrying out a correct evaluation and management of chemical risk . These tools make the necessary information for an effective implementation of the two current EU reference regulations available  (1907/2006 - REACH  Registration, Evaluation, Authorisation of Chemicals and 1272/2008 CLP - Classification, Labelling, Packaging).

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Dermal absorption of chemicals

The factsheet regards exposure to chemicals by dermal absorption.  

Chemicals, even if not irritating and corrosive, may be absorbed in significant amounts through large contact areas of non-damaged skin: their systemic toxic effects cannot be prevented only by environmental monitoring; besides, damaged skin requires more precautions. 

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ISSA-Instruction Storage of Chemicals

Safe storage of chemicals is not only relevant in chemical plants; the products in the following examples are also chemicals:

  • Paint and varnishes of a painter workshop,
  • Cleaning and disinfecting agents of a cleaning company,
  • Oils, solvents and thinners in a repair shop,
  • Building foams, cement residue remover of a construction company,
  • Gas bottles with acetylene, oxygen, liquefied gases of a locksmith.

As indicated in various legal and technical standards, the instruction of workers for safety topics is crucial.

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Occupational Exposure Limits

Occupational exposure limits (OELs) are important evaluation criteria for determining possible exposure of dangerous chemical substances and the appropriate technical, organisational, and, in certain cases, personal protective measures at the workplace. Depending on the hazard potential of substances or on the possible exposure route, different states and communities have developed different procedures for determining limit values and additional notations.

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Safe nanotechnology on workplaces

Sorry, this article is only available in the original italian version.

Click here for an abstract in English.

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Labelling of Chemicals

The characterization/labeling of chemicals is an important requirement for an unambiguous hazard communication. However, there are differences between putting chemicals on the market and the activities with chemicals in the enterprise. In the brochure the legal duties of the entrepreneur regarding both fields as well as recommendations for the practical implementation for the user have been put together.

Sorry, this article is only available in the original german version.

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Buy extraction units – but in the right way!

The information “buy extraction units – but in the right way!” (I 7006-2) is very new and supports enterprises to consider important data before buying extraction units.

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Storage of Chemicals

How are chemicals stored safely? This question is not only relevant in chemical plants. The products in the following examples are also chemicals:

  • Paint and varnishes of a painter workshop
  • Cleaning and disinfecting agents of a cleaning company
  • Oils, solvents and thinners in a repair shop
  • Building foams, cement residue remover of a construction company
  • Gas bottles with acetylene, oxygen, liquefied gases of a locksmith

This brochure shall give a practical guide to where and how chemicals should be kept, in particular for small and mediumsized enterprises.

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Mis-Identification of chemicals

Mis-Identification of chemicals is a key problem for production plants specialising in batch processing, such as are commonly encountered in the fine-chemicals and pharmaceutical industries. In this publication, hazards resulting from the mis-identification of chemicals are presented and preventive measures are described.

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ISSA Posters GHS

The "Dangerous Substances" working group within the Chemistry Section of the International Social Security Association (ISSA), in cooperation with BG RCI Prevention Section, has prepared several posters based on the European draft regulation. These posters show the new hazard pictograms and a comparison of existing and future hazard communication in terms of both physical hazards and health risks.

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Maintenance and Changes in Plants with High Safety Requirements

This brochure is focussed on hazards that are associated with maintenance and changes. It presents case studies and practical solutions to control such hazards.

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